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structure of 37853-59-1

1,1-(1,2-Ethanediylbis(Oxy))Bis(2,4,6-Tribromobenzene)(CAS 37853-59-1)

CAS No.: 37853-59-1 Brand: MolBest
M. Ft.: C14H8Br6O2 Cat. No: G6574101
M. Wt.: 687.64 MDL: No record
Storage: 2-8°C Use: For laboratory research use only
HS CODE: 2909309090 UN No.: UN 3152
Purity Grade Package Stock Price Quantity
97%
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RG 250MG In Stock 8 USD
97%
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RG 1G In Stock 13 USD
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RG 5G In Stock 70 USD
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RG 25G In Stock 211 USD
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RG 100G In Stock 803 USD
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Applications of 37853-59-1

BTBPE is predominantly used as a flame retardant in various applications such as:

  • Thermoplastics: Incorporated into plastics used in electronics and automotive components.
  • Textiles: Applied to fabrics for enhanced fire resistance.
  • Construction Materials: Used in insulation materials and coatings to reduce flammability.

Physical and chemical properties of 37853-59-1

Boiling Point

566.4±50.0 °C at 760 mmHg

Decomposition

1,2-bis-(2,4,6-tribromophenoxy)ethane (BTBPE) is currently one of the most utilised novel brominated flame retardants. In this contribution, ... the mechanisms pertinent to its thermal decomposition in view of analogous experimental findings /were analyzed in detail/. ... A 1,3-hydrogen shift, leading to 2,4,6-tribromophenol (M9) and 1,3,5-tribromo-2-(vinyloxy)benzene (M10) molecules, dominates direct scission of O-CH2 bonds up to a temperature of ~ 680 K /was demonstrated/. H atom abstraction from CH2 sites, followed by a fission of a C-C bond, produces a 2,4,6-tribromophenoxy radical (M2) and a M10 molecule. Bimolecular condensation reactions involving M2, M9 and M10 produce several congeners of brominated diphenyl ethers and their OH/OCHCH2 substituents, which serve as direct precursors for the formation of polybrominated dibenzo-p-dioxins. Reaction of M9 with a model compound of a hydrocarbon chain preferentially yields M2. Strong adsorption energy of the latter on a radical site of a hydrocarbon chain suggests that mechanisms such as Langmuir-Hinshelwood, Eley-Rideal and Diels-Alder might be operating during the formation of PBDD/Fs from brominated flame retardants (BFRs).

Density

2.58

Exact Mass

681.562439

Flash Point

238.8±28.6 °C

H Bond Acceptors

2

H Bond Donors

0

Index of Refraction

1.667

LogP

log Kow = 8.9

Melting Point

Melting point = 224 °C (commercial products are mixtures; the melting point given is for the low end of the range)

Molecular Formula

C14H8Br6O2

Molecular Weight

687.636

PSA

18.46000

Solubility

DMSO: Insoluble (<1 mg/mL at 19 °C); 95% ethanol: Insoluble (<1 mg/mL at 19 °C)

Stability

Stable. Incompatible with strong oxidizing agents.

Storage condition

2-8°C

Vapour Pressure

1.89X10-10 mm Hg at 25 °C (est)

Spectrums of 37853-59-1

Attention:
1.The NMR spectrum displayed on the page is a pre-sale reference spectrum and may differ from that of the actual received batch.
2.The accompanying documentation will include the NMR spectrum and purity analysis data for the shipped batch.
Physical sample testing spectrum (NMR) of 37853-59-1

Retrosynthesis analysis of 37853-59-1


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Download SDS of 37853-59-1

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Hazard Statements

H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

Safety Data Sheet

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